five of them are yawn, hypnosis, spore, sleep powder and sing
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yawn
For catching a zapdos.First you will need at least 20 ultraballs.Second you will need a pokemon that can sleep the rival pokemons. Now to catch zapdos first weak it and then sleep it and start throwing ultraballs at it. You will catch it after 10,11 or 12th trial
There are no items that can put Pokemon to sleep, only moves like hypnosis and sleep powder.
snorlax
sleep powder catch a butter free and level it up afew times then it will try to learn sleep powder