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At this time you can not, you must go to the PlayStation Store to buy games
The Complete Playstation Store is not on the part of the Playstation Network that you access from the PC and you will be able to buy and download from the PS3. You can not download and load and play games into a PS3 harddrive except from the Playstation Store.
You'll have to buy the costume pack in the ps3 store.
According to Best Buy's official website, the PlayStation 3 is sold in a bundle. The "Holiday Bundle", which comes with two games is priced at $289.99.
From the store. The release date is the 18th December 2013 for PS3, PS4 and PS Vita.