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If you're talking about the smite enchantment, then no. Smite affects Zombies and Skeletons.
Smite increases damage against zombies, skeletons and zombie pigmen.
Smite is an enchantment you can put on swords. With it, you can do extra damage to zombies, zombie pigmen, and skeletons.
It makes the sword stronger against undead foes
Smite increases damage to undead mobs."Each level separately adds 2.5 ( × 2 1/2) extra damage to each hit, to "undead" mobs only" - gamepedia