It makes the sword stronger against undead foes
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the smite enchantment in minecraft makes it so your sword does extra damage do zombies, skeletons and pigmen.
That all depends on what you want to accomplish using the sword. If you want to kill undead mobs easier, then smite. If you want to push back mobs, then knockback.
If you're talking about the smite enchantment, then no. Smite affects Zombies and Skeletons.
Smite is an enchantment you can put on swords. With it, you can do extra damage to zombies, zombie pigmen, and skeletons.
Smite increases damage against zombies, skeletons and zombie pigmen.