In Pokémon Emerald, Pikachu is capable of learning moves such as Thunder Wave, Thunderbolt, Tail Whip, Quick Attack, Slam, Double Team, Agility, Light Screen and Thunder. Additionally it can be taught TMs such as Toxic, Focus Punch, Hidden Power, Rain Dance, Protect, Return, Frustration, Iron Tail, Brick Break, Dig, Shock Wave, Secret Power, Facade, Attract and Rest.
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no
Aggron doens't learn rock slide in this version
No, Pikachu is not capable of learning Electro Ball in Pokémon Emerald. Pokémon Emerald is a Generation 3 game and Electro Ball was a Pokémon attack that was created and introduced for the Generation 5 games.
defog is not in emerald,
the Pokemon that can use thief are ralts,lotad,mightyena and other dark and psyic Pokemon i cant think of.