Wobbuffet is unable to learn any HM/TM except the breeding moves taught to Wynaut, Counter, and Safeguardfrom the Move tutor for one heart scale in Fallarbor
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Wobbuffet cannot learn any TMs or HMs. The only moves it can know are it's own moves, Wynauts moves, Wynaut's eggmoves, counter, and safeguard from the move tutor in fallarbor for a heartscale.
I think: Psychic, Confusion, Tackle and Karate Chop.
If you have female wobbuffet with a male and vice versa. An egg you get after breeding a wobbuffet is a wynaut.
Nincada is a fantastic Pokemon to use these moves on. Not only can it learn Flash and Rock Smash, but also Cut, Dig, and Secret Power which are all moves that are required later on.
Trapinch. You can catch it in the desert. And if you just want a Pokemon to not flee there is also Wynaut and Wobbuffet.