Lugia will be lvl 50 or 72, depending on where you get it....
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Lugia learns Aeroblast at level 85.
LEVEL 85 ______________________________________ Learn Lugia Aeroblast .:.:.:.:.:.:.:.
Lugia learns Sky Attack at level 99.
lugia learns aeroblast at lv89 or lv90
Lugia can't learn psychic on its own, but you can teach it through TM29.