Sceptile cannot learn Frenzy Plant via level-up. It can only be learned via Move Tutor.
In D/P/Pt: an elderly man appears on Route 228 in the Battle Zone, and will teach it to the three fully evolved Grass-type starters of the previous generations, as well as Torterra. He will also require that the Pokémon that is to learn the move has a high happiness rating.
In HG/SS: the Move Tutor that can teach Frenzy Plant, as well as Blast Burn and Hydro Cannon to their Corresponding Pokémon, can be found in the Move Deleter/Move relearner's house in Blackthorn City (West of the Pokémon Center).
In B/W: the Move Tutor that can teach Frenzy Plant appears in a house on Route 13, and will teach it to the four fully evolved Grass-type starters of the previous generations, as well as Serperior. Like in previous generations, this move tutor will require that the Pokémon he teaches the move to has a high happiness rating.
For more information on Sceptile and Frenzy Plant, visit the following website:
bulbapedia.bulbagarden.net
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Only Treeko can learn Mega Drain at level 26 in all games. It evolves into Grovyle at level 16 and into Sceptile at level 36.
Sceptile, to my knowledge, is incapable of learning Night Slash.
100
Sceptile learns false swipe at level 59. This Pokemon evolves from Grovyle at level 36. Sceptile is a final form but using a mega evolution stone, does have a mega evolution.
he learns leaf storm at leval 67.