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Sceptile cannot learn Frenzy Plant via level-up. It can only be learned via Move Tutor.
In D/P/Pt: an elderly man appears on Route 228 in the Battle Zone, and will teach it to the three fully evolved Grass-type starters of the previous generations, as well as Torterra. He will also require that the Pokémon that is to learn the move has a high happiness rating.
In HG/SS: the Move Tutor that can teach Frenzy Plant, as well as Blast Burn and Hydro Cannon to their Corresponding Pokémon, can be found in the Move Deleter/Move relearner's house in Blackthorn City (West of the Pokémon Center).
In B/W: the Move Tutor that can teach Frenzy Plant appears in a house on Route 13, and will teach it to the four fully evolved Grass-type starters of the previous generations, as well as Serperior. Like in previous generations, this move tutor will require that the Pokémon he teaches the move to has a high happiness rating.
For more information on Sceptile and Frenzy Plant, visit the following website:
bulbapedia.bulbagarden.net
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Sceptile, to my knowledge, is incapable of learning Night Slash.
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