It doesn't leart sunny day by leveling up. It can only learn it with a TM.
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It doesn't learn Sunny Day through level up. It can, however, learn it through TM.
Earthquake Flamethrower Rock Slide Take Down/Hyper Beam OR Earthquake Flamethrower Sunny Day Solarbeam The best thing about Camerupt is its high Atk and Sp.Atk, so you should take advantage of that if you choose to use Camerupt. However, with its low defenses and Speed, it can easily faint to its quadruple weakness Water, so Camerupt isn't recommended for use at the Battle Frontier.
use a TM
Sadly No... I wish it could! The only Fire type move Lucario can learn is Sunny day.
You have to make Cherrim learn and use the move Sunny Day in battle in order for it to transform...