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You have to make Cherrim learn and use the move Sunny Day in battle in order for it to transform...
Use a move like sunny day, or use Groudon (for drought) to make it sunny. Then Cherrim will transform.
By using Sunny day, Hail, Rain Dance. Moves that It can learn
Number 59 of the Sinnoh Pokedex is Cherrim! There is an ace trainer near the Pal park that has this Pokemon. If you want to catch it, you must slather some honey on a golden honey tree and wait a few hours. Come back later and the tree should be shaking, (if it is not then click on the tree, if it says "The tree is slathered with honey..." then the Pokemon hasn't come yet. However if it says "There is a sweet scent in the air... would you like to slather the tree in honey" then the Pokemon has already come and taken the honey because you have left it to late.) If the tree is shaking then click on it. You should go into battle, there are quite a few Pokemon you could find on a honey tree but one of the is Cherubi. (Who evolves into Cherrim!) Catch the Cherubi! Train it up to level 24 or 25 and it should evolve into Cherrim. P.S. When Cherubi gets to level 22 it should try to learn Sunny Day, make it learn it then once you have evolved it into Cherrim use Sunny Day in battle and you will get a surprise!
its like castform keep it from being sunny