Iron Head is learned via tutoring
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I do not even think it, i now it! Scizor learns IRON HEAD by leveling up! Train it up until it reaches Level 54 or Level 55 and KAPOOW, you have af Scizor With the nice and powerfull attack, IRON HEAD. Hope this helped:-D
Iron Thorn Z Pokemon Questions HelperAnswer: Rampardos learns Head Smash at level 53. Hope That Helped!
pikachu learn iron tail at lvl 60
In Pokémon Platinum, the moves that Steelix is capable of learning via level up include ones such as Tackle, Bind, Harden, Mud Sport, Thunder Fang, Fire Fang, Ice Fang, Rage, Screech, Rock Throw, Sandstorm, Rock Tomb, Slam, Rock Polish, Iron Tail, Dragonbreath, Double-edge, Stone Edge and Crunch.
You can't teach Scyther any steel type moves, you have to evolve it by trading it while it is holding the metal coat. When it evolves into Scizor, that is when it can learn steel moves. It learns metal claw at level 21, iron defense at level 37, and iron head at level 53.