Blast burn is a special move. You can't get it from leveling up. Charizard/ Venasuar/ Blastoise each have a special move they can learn at cape brink. The move is dependent on your starter pokemon.
charmander-Blast Burn
bulbasuar- Frenzy Plant
squirtle- HydroCannon
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to let blaziken to learn blast burn is trade it for a charizard then you need to catch a latias (this is only for sapphire) then level it up to level 100 then after that put charizard at first in your party then summary it then their will be a bad egg at your party after it hatches you have to turn it off (this is not true ) this is the truth hatch it with a charizard who knows blast burn.
No, Arcanine cannot learn Blast Burn because it is not a starter Pokemon. Infernape, Charizard, and other fire type starters can learn blast burn.
Charizard can't learn flare blitz because its not a move, maybe your talking about Blast burn it needs to be level 50 to learn it then go to two island and go north to a house go in and talk to the lady show her your charizard and she will teach it blast burn.
hyper beam, blast burn, flamethrower, fire blast, giga impact ,wing attack,slash,metal claw
talk to that old hag on 2 island at the top of it and have your charizard with you and she'll say your Pokemon sucks let me teach it blast burn