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Blast burn is a special move. You can't get it from leveling up. Charizard/ Venasuar/ Blastoise each have a special move they can learn at cape brink. The move is dependent on your starter pokemon.

charmander-Blast Burn
bulbasuar- Frenzy Plant
squirtle- HydroCannon

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Q: What level does Charizard learn blast burn?
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