Ambipom can't learn Bounce via level up or via a TM but a Move Tutor within Route 226 (that you need to Rock Climb to get to) can teach Bounce to Ambipom for 4 Red Scales, 2 Yellow Scales and 2 Green Scales.
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Ambipom doesn't learn fake out. Fake out is an "egg move" that Aipom learns by breeding a Male Pokemon that knows Fake Out with a female Aipom/Ambipom.
If you go to the move tutor in the higher level of the survival area.You need to rock climb on the rocks that are on the west side.The move tutor there will teach your Ambipom bounce for 4 red shards 2 yellow shards and 2 green shards.
Only if the Ambipom is Male and knows Bounce. If it doesn't know bounce and is Female, breed it with a Male Ponyta, Rapidash, Wailmer, Wailord, Spoink, Grumpig, Buneary, or Lopunny who knows bounce.
i have one it learns bounce on level 46
You can get an Aipom by spreading honey on honey trees. After that, evolve it into an Ambipom by making it learn Double Hit at Level 32, then it will evolve.