i have one it learns bounce on level 46
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What level Rapid ash learns the move Bounce depends on your version of the game. In Pokemon Ruby, Sapphire, Emerald, FireRed and LeafGreen Rapid ash learns Bounce at level 50. In Pokemon Diamond and Pearl it learns Bounce at level 49. In Pokemon Platinum, HeartGold and SoulSilver it learns Bounce at level 47. And finally from Pokemon Black and White onwards Rapidash will learn Bounce at level 45.
Ambipom can't learn Bounce via level up or via a TM but a Move Tutor within Route 226 (that you need to Rock Climb to get to) can teach Bounce to Ambipom for 4 Red Scales, 2 Yellow Scales and 2 Green Scales.
Sky uppercut is the final move that Combusken learns. It will learn to do this move at level 59.
Yes, if you use a rare candy to level it up to a level where it learns a move, it will still prompt you to learn the move.
Level 13