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Xaverian College is located in Manchester, England. It begins with the letter X.
Xena
Xi River is the name of a river in China. Xingu River is the name of a river in Brazil.
There are no cities or towns in Montana that begin with X. If you need X for Montana, Xit Road is the name of a street in Terry, Montana. Xeno Road is the name of a street in Chinook, Montana.
X-rayXenonXeroxSince the question asked for "three-letter" words beginning with "X", how about "xis"?