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X-rayXenonXeroxSince the question asked for "three-letter" words beginning with "X", how about "xis"?
No country begins with the letter X.
A fruit beginning with x is Xigua which is looks similar to a watermelon, only shorter in size. x Not sure about these: xerophyte - a plant that loses very little water and can grow in deserts; xeromorph - a plant that is adapted to salt-water marshes; and, xylocarp - a hard and woody fruit. x
You can buy a xylophone in a shop. It begins with the letter x.
Xerex