my (non uber) sunny day team is as follows:
Bellosom/Bold/heat rock Lapras/Modest/Leftovers
Sunny Day Rest
Solarbeam sleep talk
Toxic Thunderbolt
Protect Ice beam
Charizard/Timid/Life orb Aerodactyl/Jolly/Leftovers
Flamethrower Stone edge
Airslash Fire fang
Solarbeam Aerial ace
Focus blast/Hidden power (of your choice) Stealth rock/roar
Arcanine/Jolly/Leftovers Weaville/Adamant/Jolly/Life orb
Morning sun Ice punch
Flare blitz Ice shard
Extreme speed Night slash
iron head/crunch Protect
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TM11 Sunny Day can be found in the Safari Zone.
Yes, the TM Sunny Day is in Pokemon Emerald. You can find it in a cave in the middle of the lake in Route 120 called Scorched Slab.
You can obtain the TM Sunny Day from the Radio Tower located in Goldenrod City.
use a TM
in the safari zone