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In my opinion, either Alakazam or Gardevoir because they both are found in the beginning (although Ralts learns confusion fast, where as Abra doesn't learn a move until level 16 when it evolves into Kadabra) and have high special attack stats. Also if you play emerald alone and don't have anyone to trade with then definitely get Gardevoir because to get Alakazam you have to trade Kadabra which sometimes is hard to do/can't do until later in the game.
This is just my opinion.
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What is the best psychic pokemon to have in emerald?
Gardevoir. It has very high special attack.
What is the best Pokemon emerald team with Torchic as starter?
-Azumarill -Magnetric -Breelom -(A flying pokemon) -(a normal, fighter or psychic)
Where can you get the TM psychic in Pokemon emerald?
You can buy it at the game corner.
Meditite Pokemon emerald?
Meditite is in Ruby, Sapphire, and Emerald. It’s Psychic/Fighting and evolves into Medicham starting at level 37.
Which Pokémons learn psychic on Pokémon emerald?
Here is a list of all pokemon that can learn Psychic: http://www.serebii.net/attackdex/psychic.shtml
