You can buy it at the game corner.
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Psychic (TM 29) is found on Victory Road, while on your way to the Pokemon League. Also I believe you can buy one on the Battle Frontier later in the game.
NOWHERE.The TM trick is not available as a TM in Pokemon Emerald
Tm. 35
This TM is given by Mr psychic in saffron city his house is to the right from the Pokemon center.
TM35.