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If youre talking about Sinnoh Pokedex the number 102 is CHATOT. ( you can find him along the beach to the west of Sunnyshore City)

If youre talking about the National Pokedex then the number 102 is EXEGGCUTE. ( i think you have to migrate him , im not sure if you can find him on Pokemon diamond or pearl- i havent but my friends got one!- sooooo... i think the best way is to migrate from either Leaf Green or Fire Red) hope it helps!!! :)

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Q: What is the Pokemon in the pokedex that is number 102 in Pokemon Diamond and Pearl?
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