xenoglossophobic which is the fear of foreign languages
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Extraterritoriality is the longest word in the English language beginning with "ex."
Bellybuttons would be the longest word I can think of beginning with a 'b' and ending in an 's'.
use a dictionary
1,909 letters in the longest word
a four letter word beginning with X is xebec (a small historical three masted sailing ship with square sails.