The longest word beginning with Z is "zyzzogeton," a type of South American leafhopper. It's a whopping 10 letters long, so get ready to impress your friends with that fun fact. Now go forth and dazzle the world with your newfound knowledge!
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Extraterritoriality is the longest word in the English language beginning with "ex."
Four letter word beginning with Z and ending with T:Zest
A three letter word beginning with z has to be Zoo
zestfully
xenoglossophobic which is the fear of foreign languages