Buy a Pokedex Book :) Diglett can learn: Move lvl Scratch - Sand Attack - Growl 5 Magnitude 9 Dig 17 Fury Swipes 21 Mud Slap 25 Slash 33 Earthquake 41 Fissure 49 Toxic TM06 Hidden Power TM10 Sunny Day TM11 Protect TM17 Frustration TM21 Earthquake TM26 Return TM27 Dig TM28 Double Team TM32 Sludge Bomb TM36 Rock Tomb TM39 Aerial Ace TM40 Facade TM42 Secret Power TM43 Rest TM44 Attract TM45 Thief TM46 Cut HM01 Rock Smash HM06
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diglett or dugtrio
Diglett evolves at level 26. It's best to try to have a Diglett battle an electric type Pokemon; since electric moves have no effect on ground types. Don't train a Diglett against a flying type Pokemon; ground moves don't affect flying types. You can also get a Dugtrio in the Diglett Cave (can be gone into outside of Vermillion City); any Dugtrio will be around level 30-33.
Gen I: at level 42 to learn all the moves(at 35 it learns flamethrower). Gen II: at 37 to learn all the moves. Gen III: at 41 to learn all the moves. Gen IV: at 47 to learn all the moves. Gen V: at 54 so it learns fire blast(really good).
Ninetales can't learn any moves on it's own. It learns moves as a vulpix before it evolves, or through TMs.
It doesn't. Pikachu learns all the moves when you evolve it it will stop learning moves.