Ninetales can't learn any moves on it's own. It learns moves as a vulpix before it evolves, or through TMs.
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Yes, Ninetales can learn Iron Tail (TM23).
Ninetales and gulpin have like 20 moves each by leveling, starter pokemon also learn many moves by leveling A pokemon can learn better moves if you neglect evolving it for a while, vulpix can learn inferno at level 50 if you can hold out on giving it a fire stone until the . (Inferno is a great move)
Many evolution stone pokemon, like Ninetales, and Simisear, do not learn moves by levelling, meaning you need to level the preform up until it learns the moves you want, and only then use the evolution stone.
Gen I: at level 42 to learn all the moves(at 35 it learns flamethrower). Gen II: at 37 to learn all the moves. Gen III: at 41 to learn all the moves. Gen IV: at 47 to learn all the moves. Gen V: at 54 so it learns fire blast(really good).
my opinion is the following: flamethrower, fire blast, will-o-wisp, and overheat.