It doesn't.
Pikachu learns all the moves when you evolve it it will stop learning moves.
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- Thundershock - Tailwhip - Quick Attack - Thunderbolt
Raichu will not learn thunder.... but pikachu can learn it at level 45
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he wont learn it because when u evolve pikachu raichu cant learn moves by itself so just teach him thunder with a TM ok Zeke out