a mild poffin is a mixture of every flavor so when you use it on a Pokemon all of its stats go up.
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Unfortunatley, there is no way to make a Mild poffin except for the one that the guy in the contest hall gives you when you first receive your poffin case. However, there is sililiar poffin called the Sharp poffin that is similiar to the mild poffin and is the same colour. It is often high-leveled. In order to get a Sharp poffin, you must have different berries (ex; Mico berry, Starf berry) and 4 other players.
in hearthome city
The Poffin maker's house, it is left from the Pokemart in Hearthome City and ask the lady in front of the Poffin Maker. If you need a poffin case go to the Pokemon Fan Club and talk to the old man at the couch.
first go to hearthome city and go to the Pokemon fan club talk to the chairman and he will give you a poffin case =p
The chances of making a Lv. 99 Poffin is very rare. Unless you cheat with an action replay or hack it.