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no way
I'm Sorry but you cant get more than 18 boxes in Pearl/Diamond
you can't catch more pokemon. you have to get rid of some pokemon.
in Veilstone City. go inside the wearhouse and its the pokeball in between the two blue boxes. HOPE I HELPED(:
Do you mean by hacking or Just playing.I don't think you can... Sorry... ANYWAY, Unless some one can correct me XD