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The first time is (Orig ep#156/ Dubbed ep#141- Bow to the prince) about 14mins into the episode

The Second and proper time he does it is when Goku is doing a kamehameha against him in episode (Orig ep#160/ Dubbed ep#145- Cell is Complete) about 12mins into the episode

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Q: What episode is it when gohan first turns super saiyan?
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