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When catching Celebi, you should have a cherish ball. Throw it and it will be an instant catch. (DO NOT USE A MASTER BALL OR ANY OTHER BALL.)
a luxry ball
it is good for catching lower level Pokemon
ultra ball i would save the masterball for the 3 dogs
In Pokemon Emerald, to obtain a Heavy Ball, you need to visit the Safari Zone extension in the Hoenn region. The Heavy Ball is a special type of Poke Ball that is more effective at catching heavier Pokemon. You can receive the Heavy Ball as a prize for participating in the Safari Zone's catching contest or by talking to the Safari Zone Warden after catching a certain number of Pokemon in the Safari Zone.