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If your talking about psychic pokemon, most get confusion and psychic (best in game) by leveling up to like second evolution. Psychic tms are pretty rare, but I always find a psychic somewhere during the game. Most psychic moves are best if your pokemon is good for them, in which you'll get them by training. Hope this helped!
There are 3 types that work best against psychic Pokemon: Bug,Rock,Ghost, and Dark.
The difference between these balls in Pokemon is the likelihood that you will catch a Pokemon with each. A master ball theoretically gives you 100% chance of catching the Pokemon, but all the rest depend on how strong the Pokemon is, and on the percentage for that particular ball. The pokeball is the least likely, then the great ball, then the ultra ball. (Then the master ball, which is the best of all.) In some of the Pokemon games there are additional types of balls that are better at catching certain types of Pokemon.
the best Pokemon to choose early inn the game are Abra and ralts.
The best psychic Pokemon on Pokemon diamond is alakazam. It can beat an infernape level 100. who carez about a dull looking Pokemon with two unusually big mustaches... ew... but I like Lugia and Espeon... and Gallade... and Gardevoir... bronzong all the way haha