the best Pokemon to choose early inn the game are Abra and ralts.
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If your talking about psychic pokemon, most get confusion and psychic (best in game) by leveling up to like second evolution. Psychic tms are pretty rare, but I always find a psychic somewhere during the game. Most psychic moves are best if your pokemon is good for them, in which you'll get them by training. Hope this helped!
the best pokemon to use is mudkip.
There are 3 types that work best against psychic Pokemon: Bug,Rock,Ghost, and Dark.
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there is no best with lots of love and care your electric Pokemon can be the best there is :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :) :)