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Okay, so since Gible is found in a cave, you may want to use a Dusk Ball since its dark in the cave. Also, once you encounter a Gible, you can try to use Quick Ball at the beginning of the battle. Another good one to use it the Timer Ball. If you hold out against Gible long enough, use the Timer Ball after there have been a lot of turns.

Hope this helps! ;)

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