(Fire, Grass and Water)
1st Gen: Charmander, Bulbasaur and Squirtle.
2nd Gen: Cyndaquil, Chikorita and Totodile.
3rd Gen: Torchic, Treecko and Mudkip.
4th Gen: Chimchar, Turtwig and Piplup.
5th Gen: Tepig, Snivy and Oshawott.
6th Gen: Fennekin, Chespin and Froakie.
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No matter what game of Pokemon you play to get all the starters you have to trade with the other versions.
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It is not possible to get all three starters in Pokemon LeafGreen without trading. This was an intended mechanic to encourage interaction between players.
Chespin, Fennekin, and Froakie. Pokemon X and Y will be released for the TCG and on 3DS in Fall 2013.
Well, there are actually 4 fire starters and they are Charmander from Kanto, Cyndaquil from Johto, Torchic from Hoenn and Chimchar from Sinnoh