In Pokemon Diamond, the Sinnoh Pokedex is barboach while In the National pokedex is Slowbro.
Barboach can be found with a good rod just about anywhere:
1. Eterna City
2. Mt. Coronet
3. Marsh Game
4. Ravaged Path
5. Underground Oreburgh City
6. Route 205
7. Route 208
8. Route 210
9. Route 212
10. Route 227
11. Route 228
All of these can be found any time of the day, generally at 30 to 35% appearance
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diamond pokedex number 80 is Barboach
Barboach and it's in mt.coronet
barboach
Pokemon #80 in Sinnoh pokedex is Barboach.
catch 80 Pokemon