I dont think Electrabuzz was introduced during the leaf green/fire red/red/ble/yellow games. It came during the Johto region. So my answer would have to be no.
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Electabuzz is version exclusive to firered.
Electabuzz
You can only catch them in Pokemon fire red.
No, electabuzz only appears in pokemon fire red as magmar also only appears in pokemon leaf green. Hope this helped!
There isn't a trainer that has scyther.