You can only catch them in Pokemon fire red.
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You can't catch one at all. You'd have to trade one from FireRed/LeafGreen.
Electabuzz is version exclusive to firered.
Electabuzz
You can catch Electabuzz. It is at the Power Plant, but it is rare.
No, electabuzz only appears in pokemon fire red as magmar also only appears in pokemon leaf green. Hope this helped!