No, electabuzz only appears in pokemon fire red as magmar also only appears in pokemon leaf green. Hope this helped!
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Electabuzz is version exclusive to firered.
Electabuzz
You can only catch them in Pokemon fire red.
You can't catch one at all. You'd have to trade one from FireRed/LeafGreen.
Piplup does not exist in Pokemon LeafGreen or FireRed.