No, but skitty can be caught on route 222 in Pokemon diamond pearl and platinum
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swarms on route 222
The only way I know is to look behind the Pokemon Mansion or to migrate one from Ruby, Sapphire, or Emerald.
You have to fly to Sandgem town and go to Lucas's/Dawn's house and talk to the little girl who's addicted to TV. She may say that the TV is talking about Skitty swarming on Route 222 which is west of Sunyshore and you will need to go there to encounter Skitty. (She may not say it's Skitty that day.)
No, Skitty is not in that generation.
If you breed a female Skitty and a male Wailord then you get a Skitty but if you breed a female Wailord and a male Skitty then you'll get a Wailmer.