No, Skitty is not in that generation.
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yes u can get riolu in Pokemon heart gold and soul silver you catch him or her in the safari zone and you can catch lucario in the safari zone two.
Yes you can catch it in soul silver it in safari zone.
their outside in the grass in front of the safari zone
In HeartGold you can find Larvitar on Mt. Silver or in the Safari Zone (in the 'Mountain' area).Safari Zone
You can catch a Misdreavus on Mt. Silver, The Cliff Cave, or the Safari Zone (has special requirements).