depends if you waant a gardevoir or a gallade
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This is a hard question to answer. The best Pokeblock would depend solely on what nature your Ralts has. The nature is what decides what pokeblocks the Pokemon would like and not the actual Pokemon type or species.
ralts sucks until it evolves into gardevoir or galade and then its an amazing Pokemon and i personally recomend gallade.^
you have to evolve a ralts to get kirlia in pearl diamond platinum ruby Sapphire or emerald ralts evolves at level 25 to15 depending on the nature but u have to have its happyness realy high
Ralts can only be obtained on Pokemon Pearl by using the PokeRadar on Routes 203 & 204-South. Ralts only has an 11% appearance rate in these areas so good luck!
any Pokemon could have a serious nature especially if you try breeding them until one with a serious nature shows up.