It is considered the hardest to capture along with Latias because you have to work very hard just to find it in the grass or water all over the hoenn region. After finally finding it you can officially get it if you use the masterball but lets say you already used it then instead you should weaken it but it will run away afterward HOWEVER now that you found it you can track it using the pokedex so it's a little less difficult to find again when you do find it again it will still be weakened when you find it now all you need to do is send out a pokemon that has an ability like shadow tag or arena trap that way you can take your time throwing ultra balls at Latios.
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How do you catch latios in Pokemon sapphire
A Pokemon's catch rate can range from 3 (hardest to catch) to 255 (easiest to catch). Hardest to catch (catch rate = 3): - Uxie - Mesprit - Azelf - Heatran - Regigigas - Giratina - Cresselia - Manaphy - Darkrai - Arceus Easier to catch (catch rate = 30): - Dialga (& Palkia) Easiest Sinnoh legendary to catch (catch rate = 45): - Shaymin
catch poocheana and zigzagagoose and then they will eat your Pokemon and then you get a free deosyxes and the latios plus jirachi and kyrogue/groudon catch poocheana and zigzagagoose and then they will eat your Pokemon and then you get a free deosyxes and the latios plus jirachi and kyrogue/groudon
you go fly in the air and catch him with a net
In Pokemon ruby you can catch latios but not latias, in Pokemon sapphire you can catch latias not latios, in emerald you can choose. Use your master balls on them so they wont fly away. You can use other types of balls, eg timer ball, ultra ball, or great ball on the other legendaries.