Video game piracy is not legal
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No you are not able to play pirated PS2 CD's in a Sony PS3. There are some PS3's that are backwards compatible and can play PS2 games.
Of Course you can you just download the game and burn it on to a writable CD; however, you Will need a modification (also know as a chip u can burn the orginals and always have the original) chip in your PS2 to make it work.
Only if the PS2 is modded with a modchip, FreeMC Boot, or CD/DVD Swap Magic.
PS3s play only PS3 games unless they say they will play others. For example most say that they will play select PlayStation titles and most say they will not play PS2 games right on the box it was shipped in. PS1 used the CD format and PS2 did not use a CD and instead used a DVD format disc. The only PS3 that said they could play PS2 games were the old PS3 consoles with 4 USB ports