Why not? It has some moderate psy power and it can make the for FLINCH on top of a KO! I suggest psybeam instead since it can confuse though, but hey man, it's your choice. Or Chuck Norris'.
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Extrasensory. Zen Headbutt is a physical type move so therefore it is subject to Pokémon that have Static, Rough Skin, etc, but Extrasensory is special type move. They have the same power so that doesn't mean anything. Also, Zen Headbutt has an accuracy of 90 while Extrasensory has an accuracy of 100. And they both may cause flinching. So therefore extrasensory is better.
Roserade can only learn extrasensory through breeding. If you have a Pokemon that already knows that move, try to breed it with Roserade.
It still doesn't!
give it a TM that you get after you beat the elite 4 (at least that's what my friend told me.)
One good move for spiritomb is dark pulse. One good move for spiritomb is dark pulse.