Yes it is a good Pokemon.
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Venusaur cannot evolve using a fire stone. Venusaur is the final regular evolution of bulbasaur though with a venusaurite Venusaur can mega evolve temporally.
breed it with a ditto or a venusaur of the opposite gender
Venusaur learns Sloarbeam at level 53.
Of course. All it needs to do is have sex (Yummy!) with a female venusaur.
Your rival will have a Venusaur if you chose Squirtle as your starter.