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It does not take long for it to get enough of a charge for the red lights to work. Plus when the item is plugged in it has power and will work as a controller while it is charging.
couple hours, but you can use it while charging with the cable attached during that 2 hours.
it takes about 3 hours from a full dead battery, A full charge lasts around 28 hours. Source myps3.com.au
AA, or you can buy controller with a battery pack so you just charge it from Xbox and don't have to worry about buying batteries all the time