Try catching a level 35 or above a level 32 is ok if there are no bug catchers
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In heart gold, you win the bug catching contest by catching the best bug type Pokemon. The score of the Pokemon you catch is based upon both it's stats and the amount of Hit Points it has left when you catch it.
win first place in the bug catching contest
No day, it will just come randomly
There on Tusday and Wendsday.
You get it in the Bug Catching Contest