You win the lotto by entering and they give you a number. If your number matches, you win. This takes alot of luck to win.
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You cannot get the Master ball back if you missed it at Team Aqua's Base. The base is blocked forever. The only way is to win the lotto at Lilycove City by matching all the numbers. Then you will receive a Master Ball.
You go to the Jubilife TV station in Jubilife City. Go up to the counter and the woman will let you draw the lotto ticket. Your lotto ticket will have 5 numbers on it. Starting from the right, if the numbers on the lotto ticket match the ID of any of you Pokemon, you win a prize. The key is to trade lots of Pokemon with your friends or by using the GTS. Hope this helps!
To win the master ball, you must pick a lotto ticket that is exactly the same as the number on the trainer's ID on one of your Pokemon (I remember that it can be in the PC). For example, my trainer ID is 33393. To win the master ball, you have to pick a lotto ticket with number 33393. If it is other numbers, you get other prizes.
When you walk it there is a woman at the desk and she'll ask you if you want the your "lotto" ticket say yes and you'll figure out the rest when you talk to her