You cannot turn it into Zen mode. It Turns into zen mode when it is low health (when the health is in the red)
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Zen Mode is not an evolution, it is an ability that some Darmanitan have. They change to Zen Mode in battle when their HP is low. To get a Darmanitan that can do this, you need to get a Darumaka from the Global Link website, and evolve it to Darmanitan. Also, you can use a rage candy bar ( you get it in winter in the ice town ) at the statues outside the desert resort. These Darmanitan have the Zen Mode ability.
It doesn't evolve into it. Zen Form is an ability. If it has the ability, then when Darmanitan has less than half its health, it will turn into Zen Form.
The pokemon with the longest name is Fletchinder, which is 11 letters long.
First, you'll have to have finished the game. Next go right up to the entrance of Relic Castles with all the statues surrounding it. Professor Juniper should come to you and give you a RageCandyBar. Finally, go to any of the statues and press A. You'll encounter a wild Darmatian in Zen Mode. Once you catch it, it will only turn into its Zen Mode when it has low health (in the red area).
After you complete the main game, go to the relic castle again, off route 4. There are a number of 'sleeping' (Zen Mode) Darmanitan around the entrance. Professor Juniper will appear if you try to enter, and give you a RageCandyBar, which can wake one up and let you battle it.