Zen Mode is not an evolution, it is an ability that some Darmanitan have. They change to Zen Mode in battle when their HP is low.
To get a Darmanitan that can do this, you need to get a Darumaka from the Global Link website, and evolve it to Darmanitan.
Also, you can use a rage candy bar ( you get it in winter in the ice town ) at the statues outside the desert resort. These Darmanitan have the Zen Mode ability.
Darumaka evolves into Darmanitan at level 35.
Darumaka evolves at level 35.
Darumaka evolves at level 35
Get it to lv. 35
darumaka evolves into darmanitan at level 35 or level 70 on Pokemon white
Darumaka can ONLY evolve into Darmanitan. Some Darmanitan can undergo a forme change to Zen mode when their HP is low, but it is not a 'different pokemon'.
darmanitan in zen and regular mode
you can either: A: evolve darumaka at lvl 35 B: expose a ragecandybar to one of the statues outside of the relic castle to get a special darmantian with the ability zen mode.
it evolves when it reaches level 35 or you can get the evolution if you have the ragecandybar from Pro. Juniper and go near the entrince to relic castle give it to the statue/Darmanitan then try to catch it (catch rate: 60) and its zen mode is fire and psychic type but its normal form is only fire =)level 35.
Darumaka evolves into Darmanitan at level 35.
Darumaka evolves at level 35.
Darumaka will attempt to evolve once it reaches Level 35.
Darumaka evolves to Darmanitan at Level 35.
Darumaka evolves at level 35
Get Darumaka to Level 35 in order to evolve it into Darmanitan.
Darmanitan
Get it to lv. 35