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First, you'll have to have finished the game. Next go right up to the entrance of Relic Castles with all the statues surrounding it. Professor Juniper should come to you and give you a RageCandyBar. Finally, go to any of the statues and press A. You'll encounter a wild Darmatian in Zen Mode. Once you catch it, it will only turn into its Zen Mode when it has low health (in the red area).

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Q: How do you get darmanitan in zen mode?
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